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An efficient and recyclable palygorskite-supported palladium catalyst for Suzuki–Miyaura coupling reactions in water at room-temperature

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Abstract

A highly efficient heterogeneous catalyst (Pd@Fun-PGS) is successful prepared by palladium immobilized on the surfaces of palygorskite via a simple method. After functionalization of the natural palygorskite under mild conditions, a large number of effective binding sites are produced, which perform high catalytic activity in water under mild conditions for a wide scope of Suzuki–Miyaura coupling reactions without phosphine ligand. The novel catalyst is characterized by FT-IR, XRD, XPS, SEM and TEM. It is worth noting that the efficient and stable catalyst could be easily reused for at least 8 times with inappreciable metal leaching. The catalyst system has potential applications in organic synthesis and is expected to further expand the utilization of clay in the catalytic field.

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Acknowledgements

This work was financially supported by the Natural Science Foundation of Gansu Province (No. 22JR5RA215). We also thank Key laboratory for Utility of Environmental Friendly Composite Materials and Biomass in University of Gansu Province (Northwest Minzu University), for financial support.

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Authors and Affiliations

  1. Key Laboratory of Environment-Friendly Composite Materials of the State Ethnic Affairs Commission, Gansu Provincial Biomass Function Composites Engineering Research Center, Key Laboratory for Utility of Environmental-Friendly Composites and Biomass in University of Gansu Province, College of Chemical Engineering, Northwest Minzu University, Lanzhou, 730030, People’s Republic of China

    Yuzhi Sun, Penghui Zhang & Shang Wu

  2. College of Chemical Engineering, Lanzhou University of Arts and Science, Beimiantan 400, Lanzhou, 730000, Gansu, China

    Yang Liu & Quanlu Yang

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  1. Yuzhi Sun
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  2. Penghui Zhang
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  3. Yang Liu
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  4. Shang Wu
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  5. Quanlu Yang
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Correspondence to Yuzhi Sun.

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Sun, Y., Zhang, P., Liu, Y. et al. An efficient and recyclable palygorskite-supported palladium catalyst for Suzuki–Miyaura coupling reactions in water at room-temperature. Reac Kinet Mech Cat 137, 163–176 (2024). https://doi.org/10.1007/s11144-023-02533-6

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